Photodiode structures & materials

- a summary of the different types of photodiode structure and photodiode materials that are used for PN, PIN,avalanche and Schottky photodiodes..

Although ordinary diodes exhibit photodiode properties, it is necessary to adopt the right photodiode structure and to use the right photodiode materials to ensure that the performance is optimised.

A variety of different photodiode structures are used and these vary according to the type of photodiode in question. Avalanche photodiode structures are different to those used for PIN or PN photodiodes. The Schottky photodiode structure is again different. However all the photodiode structures are designed to optimise the light collection and conversion

PIN / PN photodiode structure

Although an ordinary p-n junction can be used as the basis of a photodiode, the p-i-n junction provides a far more satisfactory photodiode structure. In the photodiode fabrication process a thick intrinsic layer is inserted between the p-type and n-type layers. The middle layer may be either completely instrinsic, or very lightly doped to make it and n- layer. In some instances it may be grown as an epitaxial layer onto the substrate, or alternatively it may be contained within the substrate itself.

PIN photodiode structure
PIN photodiode structure

One of the main requirements of the photodiode is to ensure that the maximum amount of light reaches the intrinsic layer. One of the most efficient ways of achieving this is to place the electrical contacts at the side of the device as shown. This enables the maximum amount of light to reach the active area. It is found that as the substrate is heavily doped, there is very little loss of light due to the fact that this is not the active area.

As light is mostly absorbed within a certain distance, the thickness of the intrinsic layer is normally made to match this. Any increase in thickness over this will tend to reduce the speed of operation - a vital factor in many applications, and it will not improve the efficiency greatly.

It is also possible to have the light enter the photo diode from the side of the junction. By operating the photo diode in this fashion the intrinsic layer can be made much less to increase the speed of operation, although the efficiency is reduced.

In some instances a heterojunction may be used. This form of structure has the additional flexibility that light can be received from the substrate and this has a larger energy gap which makes it transparent to light.

PIN photodiode heterojunction structure
PIN photodiode heterojunction structure

The heterojunction format for a PIN photodiode uses less standard technology often using materials such as the InGaAs and InP depicted in the diagram. Being a less standard process, it is more expensive to implement and as a result tends to be used for more specialist products.

PN / PIN photodiode materials

The materials used within a photodiode determine many of its critical properties. The wavelength of light to which it responds and the level of noise are both critical parameters that are dependent upon the material used in the photodiode.

The wavelength sensitivity of the different materials occurs because only photons with sufficient energy to excite an electron across the bandgap of the material will produce significant energy to develop the current from the photodiode.

Material Wavelength
sensitivity (nm)
Germanium 800 - 1700
Indium gallium arsenide 800 - 2600
Lead sulphide ~1000 - 3500
Silicon 190 - 1100

Wavelength ranges for commonly used photodiode materials

While the wavelength sensitivity of the material is very important, another parameter that can have a major impact on the performance of the photodiode is the level of noise that is produced. Because of their greater bandgap, silicon photodiodes generate less noise than germanium photodiodes. However it is also necessary to consider the wavelengths for which the photodiode is required and germanium photodiodes must be used for wavelengths longer than approximately 1000 nm.

Avalanche photodiode structure

The avalanche photodiode structure is relatively similar to that of the more commonly used PN photodiode structure or the structure of the PIN photodiode. However as the avalanche photodiode is operated under a high level of reverse bias a guard ring is placed around the perimeter of the diode junction. This prevents surface breakdown mechanisms.

Avalanche PIN photodiode structure
Avalanche PIN photodiode structure

Avalanche photodiode materials

Like the standard PN or PIN photodiodes, the materials used have a major effect on determining the characteristics of the avalanche diode.

Material Properties
Germanium Can be used for wavelengths in the region 800 - 1700 nm. Has a high level of multiplication noise.
Silicon Can be used for wavelengths in the region between 190 - 1100 nm. Diodes exhibit a comparatively low level of multiplication noise when compared to those using other materials, and in particular germanium.
Indium gallium arsenide Can be used for wavelengths to 1600 nm and has a lower level of multiplication noise than germanium.

Commonly used avalanche photodiode materials

For optimum noise performance the large difference in the ionisation coefficients for electrons and holes is needed. Silicon provides a good noise performance with a ratio between the different coefficients of 50. Germanium and many group III-V compounds only have ratios of less than 2. While the noise performance of these materials is much inferior, they need to be used for longer wavelengths that require the smaller energy gap offered.

By Ian Poole

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Read more about semiconductor diodes . . . . .

•  Diode types •  PN junction •  Diode specifications •  Gunn diode
•  IMPATT diode •  Laser diode •  Photo diode •  PIN diode
•  Schottky diode •  Step recovery diode •  Tunnel diode •  Varactor diode
•  Zener diode •  Light emitting diode •  BARITT diode •  Backward diode

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Co-authored by Bernd Hantsche, Head of the GDPR Team of Excellence and Marketing Director Embedded & Wireless and Richard Ward, ‎Semiconductor Marketing Manager at Rutronik. is operated and owned by Adrio Communications Ltd and edited by Ian Poole. All information is © Adrio Communications Ltd and may not be copied except for individual personal use. This includes copying material in whatever form into website pages. While every effort is made to ensure the accuracy of the information on, no liability is accepted for any consequences of using it. This site uses cookies. By using this site, these terms including the use of cookies are accepted. More explanation can be found in our Privacy Policy